A Solid-state Silver Ion Selective Electrode Based on Polyaniline/Eosin Y Nanocomposite Film
نویسنده
چکیده
Potentiometric sensor based on commercial pencil graphite electrodes coated with polyaniline (PAni) composite with Eosin Y (EY) termed as PGE/PAni-EY have been developed for potentiometric determination of silver ion. The electrode exhibited linear response with Nernstian slope of 57.6±0.8 mV per decade within the range of 1.0×10 to 1.0×10 M with limit of detection 6.5×10 M silver ion. Fast and stable response time of the electrode (15 s) was obtained over the concentration range of 1.0×10 M to 1.0×10 M. This electrode was also used as indicator electrode in potentiometric titration of halide ions successfully. This study shows that the introduced electrode (PGE/PAni-EY) is highly selective toward silver ion and can be used to determine silver ions in solutions with high accuracy and precision. KeywordsSilver electrode, Potentiometry, Polyaniline, Eosin Y, Nanocomposite
منابع مشابه
Highly Sensitive Amperometric Sensor Based on Gold Nanoparticles Polyaniline Electrochemically Reduced Graphene Oxide Nanocomposite for Detection of Nitric Oxide
A sensitive electrochemical sensor was fabricated for selective detection of nitric oxide (NO) based on electrochemically reduced graphene (ErGO)-polyaniline (PANI)-gold nanoparticles (AuNPs) nanocomposite. It was coated on a gold (Au) electrode through stepwise electrodeposition to form AuNPs-PANI-ErGO/Au electrode. The AuNPs-PANI-rGO nanocomposite was characterized by Field Emission Scanning ...
متن کاملPerformance of miniaturised thick-film solid state pH sensors
The performance of novel solid state Thick-Film pH sensors for water quality sampling that are designed for deployment in remote catchment areas is described. These miniaturised screen printed planar pH sensors are an alternative to conventional glass pH electrodes that have many disadvantages such as high-cost, large size, mechanical fragility and limited shape. The approach adopted here for i...
متن کاملAll-Solid-State Sodium-Selective Electrode with a Solid Contact of Chitosan/Prussian Blue Nanocomposite
Conventional ion-selective electrodes with a liquid junction have the disadvantage of potential drift. All-solid-state ion-selective electrodes with solid contact in between the metal electrode and the ion-selective membrane offer high capacitance or conductance to enhance potential stability. Solution-casted chitosan/Prussian blue nanocomposite (ChPBN) was employed as the solid contact layer f...
متن کاملBiosensor for detection of selective anticancer drug gemcitabine based on polyaniline-gold nanocomposite
Electrochemical biosensor is an effective tool for pharmaceutical analysis due to its simplicity, specificity, sensitivity, fast, costeffective and repetitive measurements with miniaturized and portable devices. The paper illustrates the detail methodology for development of an amperometric biosensor based on polyaniline-gold nanocomposite film modified horseradish peroxidase for anticancer dru...
متن کاملPreparation of Low Cost Solid State Silver Sulfide Based Bromide Selective Electrodes
Preparation and performance of a cost effective silver sulfide based bromide selective membrane is described. A solid contact between membrane and body of the electrode was examined as an ion-selective electrode by determining S 2and Br ions by direct potentiometry. A linear response to bromide ion from 2 x 10 -5 to 10 -1 M with a slope of 57.3 mV per decade [Br ] is observed. The membrane has ...
متن کامل